Crystallization features of calcium sulfate in the process of “artificial aging”

Автор: Garkavi M., Fischer H.-B., Kolodezhnaya E.

Журнал: Вестник геонаук @vestnik-geo

Рубрика: Научные статьи

Статья в выпуске: 9 (309), 2020 года.

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Gypsum binders are widely used in construction, mining and the oil and gas industry. The use of these binders is conditioned by stability of their technical characteristics, which is achieved by using a technological operation “artificial aging”. The features of artificial aging are: 1) hydration of calcium sulphate hemihydrate in liquid phase deficiency; 2) the resulting dihydrate gypsum crystallizes in a limited volume of micropores of the original binder. From the standpoint of the quataronic concept, the features of the crystallization of gypsum dihydrate in the micropores of the original gypsum binder are considered. The effect of artificial aging conditions and the degree of supersaturation on the growth mechanism and the morphology of gypsum dihydrate crystals was determined. The use of artificial “aging” results in healing of defects in the structure of the original binder, decreasing water demand and increasing strength.

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Crystallization of quataron, calcium sulfate, artificial aging, gypsum binder

Короткий адрес: https://sciup.org/149129445

IDR: 149129445   |   DOI: 10.19110/geov.2020.9.6

Список литературы Crystallization features of calcium sulfate in the process of “artificial aging”

  • Askhabov A. M. Kvataronnaia kontceptciia: osnovnye idei i nekotorye prilozheniia (The quataronic concept: basic ideas and some applications). Proceedings of Komi SC UB RAS, 2011, No. 3 (7), pp.70—77.
  • Askhabov A. M. Nanoclasternaia model obrazovani-ia zhidkoi vody (Nanocluster model of liquid water formation). Proceedings of Komi SC UB RAS, 2016, No. 1 (25), pp.62—67.
  • Golik V. I., Razorenov Yu. I., Polukhin O. N. Ispolzovanie kompozitnykh viazhushchikh v gornom proizvodstve (The use of composite binders in mining). Dry construction mixtures, 2014, No. 6, pp.17—20.
  • Greg S., Sing K. Adsorbtciia, udelnaia poverkhnost, poristost (Adsorption, specific surface, porosity). Moscow: Mir, 1984, 306 p.
  • Linnikov O. D. Mehanizm formirovaniia osadka pri spon-tannoi kristallizatcii solei iz peresyshchennykh vodnykh rastvo-rov (The mechanism of sediment formation during spontaneous crystallization of salts from supersaturated aqueous solutions). Uspekhi khimii, 2014, V.84, No. 4, pp. 343—364.
  • Melikhov I. V. Fiziko-himicheskaia evoliutciia tverdo-go veshchestva (Physicochemical evolution of solids). Moscow: BINOM. Laboratory of knowledge, 2012, 309 p.
  • Mayorov A. E., Paleev D. Yu. Sostoianie izoliatcii gornykh vyrabotok shakht Kuzbassa (The state of isolation of mine workings in the mines of Kuzbass). Bulletin of the Kuzbass State Technical University, 2019, No. 3, pp. 60—65.
  • Polak A. F., Babkov V. V., Andreeva E. P. Tverdenie min-eralnykh viazhushchikh veshchestv (Hardening of mineral binders). Ufa: Bashk. book publishing house, 1990, 216 p.
  • Rashkovich L. N. Atomno-silovaia mikroskopiia protcessov kristallizatcii v rastvore (Atomic force microscopy of crystallization processes in solution). Soros educational journal, 2001, V. 7, No.10, pp. 102—108.
  • Ustinova Yu. V., Sivkov S. P., Barinova OP, Sanzharovsky A. Yu. Vliianie razlichnykh dobavok na morfologiiu kristallov dvu-vodnogo gipsa (Influence of various additives on the morphology of gypsum dihydrate crystals). Vestnik MGSU, 2012, No. 4, pp. 140—144.
  • Chetvertneva I. A., Teptereva G. A., Shavshukova S. Yu., Konesev V. G. Poiavlenie, razvitie isovershenstvovanie razlichnykh tipov burovykh rastvorov v mirovoi i otechestvennoiprak-tike (Appearance, development and improvement of various types of drilling fluids in world and domestic practice). History and Pedagogy of Natural Science, 2019, No. 2, pp. 25—29.
  • Garkavi M., Nekrasova S., Melchaeva O., Garkavi S., Fischer H.-B., Nowak S. Thermo-dynamic explanation of rational conditions of the «aging» of plaster binder. 18. ibausil. Internationale Baustofftagung, Weimar, 2012, pp. 1-0741-0748.
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