Effect of the number of active components of the catalyst on the yield of the product during the synthesis of vinyl acetate from ethylene and acetic acid
Автор: Fayzullayev Normurot, Buronov Firdavsii, Musulmonov Noriigit, Qodirov Orif, Toshboyev Feruz
Журнал: Бюллетень науки и практики @bulletennauki
Рубрика: Технические науки
Статья в выпуске: 4 т.7, 2021 года.
Бесплатный доступ
The development of active and selective catalysts for the synthesis of vinyl acetate from ethylene and acetic acid, the effect of the amount and ratio of individual components of the catalyst to control the catalytic properties of the introduced components were studied. In vinyl acetate synthesis, the effects of each component were studied to describe the effect of catalyst constituents on its properties, and empirical one-factor mathematical dependencies were obtained. Their generalized mathematical relationships of the activities of the catalysts, defined as the rates of the reactions of the formation of vinyl acetate and CO2, have been proposed. As a result of the research, a mathematical model was proposed to select the most optimal composition of the catalyst. The activity of the catalyst containing 0.4%Pd+4%Cu+7%CH3COOK/HSZ averaged 700 g VA/(l×cat×h) at 93-97% selectivity of ethylene - vinyl acetate formation.
Vinyl acetate, acetic acid, exothermic process, catalyst preparation methods
Короткий адрес: https://sciup.org/14120947
IDR: 14120947 | DOI: 10.33619/2414-2948/65/34
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