Physicochemical model of sodium silicate melt and thermodynamics of Q n-species

Автор: Koroleva Olga Nikolaevna, Tupitsyn Aleksey Albertovich, Bychinskiy Valeriy Alekseyevich

Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry

Рубрика: Физическая химия

Статья в выпуске: 36 (295), 2012 года.

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The basis of a formed physicochemical model of sodium silicate melt is a conception about Q n-species (SiO 4 tetrahedron with different numbers of bridging and non-bridging oxygen atoms). A correction of modeling results according to high-temperature Raman spectroscopy data has allowed us to propose an amendment on thermodynamic properties of Q n-species. Obtained results permit to describe a structure and properties of a melt in the range of composition from pure SiO 2 up to sodium orthosilicate in temperature diapason from 700 up to 2000 K.

Physicochemical model, silicate melts, melt structure, thermodynamic functions correction, thermodynamic potentials minimization

Короткий адрес: https://sciup.org/147160246

IDR: 147160246

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