Kinetic characteristics of hexachlorocyclotriphosphazatriene and pyridine N-oxide reaction in mixed organic solvents in presence of water
Автор: Vapirov V.V., Zaytsev D.O.
Журнал: Ученые записки Петрозаводского государственного университета @uchzap-petrsu
Рубрика: Физико-математические науки
Статья в выпуске: 6 (151), 2015 года.
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Hexachlorocyclotriphosphazatriene reacts with pyridine N-oxide to form onium salt. This salt is an intermediate product of hexachlorocyclotriphosphazatriene hydrolysis. The reaction is characterized as a first-order reaction with respect to both phosphazene and N-oxide. The water produces a catalytic effect on the investigated process. The catalytic role of the water consists in the solvation of the leaving group, which helps in its disintegration.
Chemical kinetic, reaction mechanism, phosphazene
Короткий адрес: https://sciup.org/14750942
IDR: 14750942