Structural diversity of 1,3,4,6-tetracarbonyl compounds, their analogues and nitrogen containing derivatives (review)

Автор: Karmanova Olga Gennadyevna, Kozminykh Vladislav Olegovich, Mukovoz Petr Petrovich, Kozminykh Elena Nikolaevna

Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry

Рубрика: Органическая химия

Статья в выпуске: 24 (283), 2012 года.

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The article summarizes published data and provides new information concerning the synthesis, structural diversity and properties of 1,3,4,6-tetracarbonyl compounds. Bis-1,3-diketonates are presented in solid state by (E,E)-isomer, and in solutions by dominant (E,E)- and minor (Z,Z)-isomers. Structure peculiarities and mass fragmentation of 1,6-dialkyl-3,4-dihydroxy-2,4-hexadiene-1,6-diones are investigated. Condensation of alkyl methyl ketones with diethyl oxalates and 1,2-diaminobenzene results in 2,3-Ais-(2-oxoalkylidene)tetrahydro-1,2,3,4-quinoxa-lines. With the help of spectral methods isomeric forms of synthesized compounds are found. Compounds containing contiguous 1,2- and 1,3-dioxo fragments look promising for fine organic synthesis and structural chemical analysis.

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Alkyl methyl ketones, oxalic condensation, 6-dialkyl-3, 4-dihydroxy- 2, 4-hexadiene-1, 6-diones, tautomeric forms, 3-bis-oxoylidene-1, 6-tetrahydroquinoxalines

Короткий адрес: https://sciup.org/147160230

IDR: 147160230

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