Oxidation of tri( o-tolyl)antimony by tert-butyl hydroperoxide. Molecular structures of bis[µ 2-oxo-tri(o-tolyl)antimony] and µ 2-oxo- bis[( tert-butylperoxy)tri( o-tolyl)antimony]

Oxidation of tri( o-tolyl)antimony by tert-butyl hydroperoxide. Molecular structures of bis[µ 2-oxo-tri(o-tolyl)antimony] and µ 2-oxo- bis[( tert-butylperoxy)tri( o-tolyl)antimony]

Автор: Sharutin V.V., Sharutina O.K., Artemeva E.V., Makerova M.S.

Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry

Рубрика: Металлоорганическая химия

Статья в выпуске: 4 т.7, 2015 года.

Бесплатный доступ

Tri( o-tolyl)antimony oxidation by equimolar amount of tert-butyl hydroperoxide in diethyl ether led to the formation of bis[µ 2-oxo-tri( o-tolyl)antimony] (1). At the molar ratio of reactants 1:2 or 1:4 µ 2-oxo- bis[( tert-butylperoxy)tri( o-tolyl)antimony] (2) has been formed. According to the X-ray analysis data, antimony atoms are in the trigonal bipyramidal coordination in molecules 1 and 2. The bond lengths Sb-O vary within the ranges 1.937(2)-2.078(2) Å (1) and 1.975(17)-2.216(15) Å (2).

Tri(ortho-tolyl)antimony, tert-butyl hydroperoxide, oxidation, bis[µ2-oxo-tri(o-tolyl)antimony], µ2-oxo-bis[(tert-butylperoxy)tri(o-tolyl)antimony], molecular structures, x-ray analysis

Короткий адрес: https://sciup.org/147160326

IDR: 147160326   |   DOI: 10.14529/chem150404

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