Получение монокристаллов гексаферрита бария свинца из раствора
Автор: Винник Денис Александрович
Журнал: Вестник Южно-Уральского государственного университета. Серия: Металлургия @vestnik-susu-metallurgy
Рубрика: Физическая химия и физика металлургических систем
Статья в выпуске: 1 т.16, 2016 года.
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Представлены результаты проведенного исследования возможности получения монокристаллических структур гексагонального феррита бария свинца из высокотемпературного раствора на основе оксида свинца методом спонтанной кристаллизации на воздухе. Для проведения экспериментов использовали резистивную печь в прецизионных ПИД регулятором температуры. Выращенные монокристаллы состава Ba1-xPbxFe12O19 при х = 0,2; 0,45; 0,8 имели характерную гексагональную огранку, размер до 3 мм. Полученные образцы исследовали с помощью растрового электронного микроскопа. Проведен также рентгенофазовый анализ полученных образцов, рассчитаны параметры ячейки. Образцы исследованы с помощью дифференциальной сканирующей калориметрии. Проведена оценка влияния замещения свинцом бария на структуру и свойства материала. Для состава Ba0,2Pb0,8Fe12O19 параметры решетки равны: a = 5,8917(12) Å, c = 23,173(3) Å, V = 696,60(19) Å3. Влияния замещения бария свинцом на свойства матрицы гексаферрита бария незначительны, что позволяет применять данную методику для получения частично замещенных по железу монокристаллических структур на основе гексаферрита бария свинца.
Феррит бария свинца, монокристаллы, магнитные материалы
Короткий адрес: https://sciup.org/147157002
IDR: 147157002 | DOI: 10.14529/met160101
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