Pseudo-morphogenesis in the shells of the Silurian rachiopods

The analysis of paleontological data, the study of mineral matter transformation involving live organisms in various rocks is important for the understanding of the events of the geological past. The aim of this work is to identify the bio-genic factor in the process of pseudo-morphogenesis in the shell sashes of the Early Silurian brachiopods from the carbonate rocks of the Chernyshev Ridge. Structural and microscopic methods (Shimadzu XRD 6000; Fourier spectrometer InfraLum FT-02; JSM 6400 JEOL; VEGA3 TESCAN; MIN-8) were used to study quartz pseudomorphoses in the sashes of four shells of the Early Silurian brachiopods Borealis sр. of Pentamerida order from the carbonate strata of the Chernyshev Ridge. The salicification of the brachiopod shell walls resulted in the complete replacement of the original carbonate skeleton with a change in its structural organization. It is established that quartz is the main mineral component of the intra-shell material and secondary dolomite crystals and newly formed calcite aggregates. The paper discusses the participation of Early Paleozoic and modern cyanobacterial symbionts in the replacement of primary calcite with quartz and the formation of quartz crystalline aggregates on the shell walls. It is shown that quartz on the surface of shell sashes and in the intra-shell substance of brachiopods has under-gone repeated transformations due to the combination of ancient and modern weathering processes