Synthesis and structure of the platinum complex [(C2H5)4N]2[PtCl6]
Автор: Tkacheva A.R.
Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry
Рубрика: Краткие сообщения
Статья в выпуске: 4 т.9, 2017 года.
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The reaction of potassium hexachloroplatinate with [(C2H5)4N]Cl in acetone synthesized the platinum complex[(C2H5)4N]2[PtCl6], the structure of which was established by X-ray analysis. Cation tetrahedral configuration is distorted: CNC valence angles are 91,4(2)° and 162,2(16)°, N-C bond lengths do not differ from each other (N-C 1,44(2) Å). Trans-angles ClPtCl (Cl(1)PtCl(11) 180,0°, Cl(21)PtCl(2) 180,0°, Cl(22)PtCl(23) 179.999(3)°.
Tetraethylammonium chloride, potassium hexachloroplatinate, acetone, tetraethylammonium hexachloroplatinate, structure, x-ray analysis
Короткий адрес: https://sciup.org/147160413
IDR: 147160413 | DOI: 10.14529/chem170412
