Synthesis and structure of osmium complex [Ph 4P] 2[OsBr 6]
![Synthesis and structure of osmium complex [Ph 4P] 2[OsBr 6]](/file/picture/147160324/synthesis-and-structure-of-osmium-complex-ph-4p-2-osbr-6.png "Synthesis and structure of osmium complex [Ph 4P] 2[OsBr 6]")
Автор: Sharutin V.V., Sharutina O.K., Senchurin V.S.
Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry
Рубрика: Металлоорганическая химия
Статья в выпуске: 4 т.7, 2015 года.
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Tetraphenylphosphonium hexabromoosmate, [Ph 4P] 2[OsBr 6] (I), has been structurally characterized after synthesis by interaction of sodium hexabromoosmate with tetraphenylphosphonium bromide in dimethyl sulfoxide. The phosphorus atoms of [Ph 4P] + cations have distorted tetrahedral coordination geometry (СPС angles are 106.23(11)°-113.23(10)°), the P-С bond lengths are 1.791(2)-1.801(2) Å). In octahedral [OsBr 6] 2- anions the Os-Br bond lengths equal 2.4752(2)-2.5020(3) Å, trаns-BrOsBr angles are 180°.
Sodium hexabromoosmate, tetraphenylphosphonium bromide, dimethyl sulfoxide, комплекс [ph 4p] 2[osbr 6], complex [ph 4p] 2[osbr 6], crystal structure, x-ray diffraction analysis
Короткий адрес: https://sciup.org/147160324
IDR: 147160324 | DOI: 10.14529/chem150402
Список литературы Synthesis and structure of osmium complex [Ph 4P] 2[OsBr 6]
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