Verification of thermodynamic parameters of a mixture of generator gas on oxygen-hydrogen fuel with an excess of one of the fuel components

Liquid gas generators (LGG) are additional firing units in the power system of liquid rocket engines (LPRE). The LGG ensure the operation of the power units of the turbopump unit (TPU) of the engine by feeding combustion products (CP) to the turbine drive. The main criteria for the efficiency of the generator gas is the complex (RT)gg and the thermodynamic properties of the mixture, depending on temperature, pressure, the degree of excess of the oxidizer and the enthalpy of the fuel, attributed to the conditions of supply to the nozzles of the GG. Changing the parameters of the generator gas leads to a change in the turbine power parameters due to its effect on the adiabatic operation of the Lad turbine. Depending on the engine circuit under consideration, CP GG can perform work in other units and elements of the engine, as well as influence many parameters of the LPRE. Among the main ones can be noted:  the power of the booster gas turbine of the booster turbopump unit (BTPU) in the case of the selection of the generator gas after the GG or turbogas after the main turbine;  the temperature of heating the refrigerant in the heat exchanger introduced in the GG;  specific impulse of a liquid rocket propulsion system (LRPS), depending on the quantity and properties of the turbogas entering the exhaust pipe of the engine (for the engine circuit without afterburning the generator gas);  mixing in the combustion chamber (CC) due to afterburning of turbogas entering the engine chamber after the turbine (for the engine circuit with afterburning of generator gas);  parameters of the firing wall of the engine in the case of using a high-temperature gas curtain by blowing generator gas into the supersonic part of the nozzle. For many pairs of fuel during combustion in GG, the nonequilibrium of combustion products is characteristic (especially in hydrocarbon fuels).Due to the fact that the combustion products (CP) during the combustion of an oxygen-hydrogen mixture, due to the simplicity of the reaction, have time to form while staying in the GG (i.e., the time of chemical equilibrium of the CP is less than or equal to the time of stay in the GG), their thermodynamic parameters can be reliably determined using programs that simulate chemical equilibrium reactions. In this article, the issue of obtaining reliable results of thermodynamic calculations of generator gas at low and high coefficients of oxidant excess is investigated. Verification of parameters obtained in the programs “Astra” and “Rocket Propulsion Analysis” with calculated values was carried out. The most suitable program for performing engineering calculations and modeling the thermodynamics of liquid gas generators has been determined.