Electron-energy spectrum of one-electronic states of the wireframe alicyclic nanostructures with the local substitution defects in

The nonempirical Hartry-Fock-Rutaan procedure in the STO-3G basis including the electrons correlation according to the Moller-Plesset perturbation theory of the second order to calculate the one-electronic energy states of the carbon-, silicon- and germanium - hydrogens nanoparticles was applied (the increasing of their sizes makes them become corresponded tetrahedral semiconductors structures). The peculiarities of the energy spectrum of one-electronic states of the investigated nanoparticles caused by the defects of substitution the central atom the element from the third or fifth group of the same period were discussed.