A model for producing polymer stabilizers of composites with a given macromolecule composition

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An attempt has been made to obtain a working technological formula that regulates the addition of comonomer over time, which ensures the synthesis of a copolymer macromolecule with a constant composition and, accordingly, with predicted properties of both the copolymer and its modified porous composite materials. Mathematical modeling is based on the theory of the kinetics of copolymerization, which takes into account the reactivity of monomers by means of copolymerization constants of reacting comonomers. The starting base was the kinetics of the copolymerization of two comonomers, significantly differing in their reactivity, which required a sequential, stepwise supply of a less reactive monomer to the reaction medium with a more active monomer. This technological technique contributes to maintaining the constancy of the initial ratio of comonomers and, accordingly, the synthesis of a copolymer with a constant composition, structure and properties. The dependence of the sequence of supply of comonomer to the reaction medium required the introduction of a generalized effective binary copolymerization rate coefficient...

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Polymer stabilizer, binary copolymerization, copolymer, composite, stabilizer composites

Короткий адрес: https://sciup.org/140248311

IDR: 140248311   |   DOI: 10.20914/2310-1202-2020-1-262-266

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