Peroxide oxidation of trimethylantimony in the presence of propenoic and 2-methylpropenoic acids
Автор: Gushchin A.V., Lakhanina E.A., Andreev P.V.
Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry
Рубрика: Химия элементоорганических соединений
Статья в выпуске: 4 т.9, 2017 года.
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Trimethylantimony bis(2-methylpropenoate) Me3Sb(O2CCМе=CH2)2 was obtained as a result of the reaction of trimethylantimony and 2-methylpropenoic acid in the presence of tertiary butyl hydroperoxide, which was confirmed by data of elemental analysis, as well as IR, 1H and 13C-NMR spectroscopy and chromatography-mass spectrometry. The yield of the product was 50%, in addition, the compound polymer was obtained. In the case of replacing 2-methylpropenoic acid with propenoic acid, only polymeric trimethylantimony propenoate was formed.
South ural state university, trimethylantimony, tert-butylhydroperoxide, 2-methylpropenoic acid, propenoic acid, bis (2-methylpropenoate) of trimethylantimony
Короткий адрес: https://sciup.org/147160412
IDR: 147160412 | DOI: 10.14529/chem170411
