Research of effectiveness of natural and modified sorbents for wastewater treatment based on mica quartzite treatment waste

Research of effectiveness of natural and modified sorbents for wastewater treatment based on mica quartzite treatment waste

Автор: Araslanova L.Kh., Salmanova E.R., Solovyeva E.A., Larkina A.A., Tuktarova I.O., Nazarov A.M.

Журнал: Nanotechnologies in Construction: A Scientific Internet-Journal @nanobuild-en

Рубрика: Rational use of natural sources

Статья в выпуске: 1 Vol.11, 2019 года.

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Results of a research of efficiency of sorbents on the basis of the waste of production and processing of micaceous quartzites (MQ), montmorillonite clays (MC) modified by humic connections (HC), received by extraction of waste brown coal are shown. Chemical composition of mica quartzite processing waste depending on the fraction size was previously investigated: element structure by method of the power-dispersive X-ray fluorescent analysis and mineral structure by method of X-ray phase analysis, for purpose of interrelation establishment between the structure of fraction and adsorptive properties of the received composite sorbents and also for the purpose of an exception as a part of MQ and, respectively, a sorbent of dangerous and toxic substances I-III of hazard classes. The efficiency of adsorption of the obtained sorbents was studied, an increase in sorption activity was found depending on composition of sorbent and method of modification (preliminary temperature processing and drawing on a surface of a sorbent of HC nano- and a microdimensional layer). It is determined that the greatest efficiency of adsorption of ions of heavy metals is observed for the sorbent which underwent temperature modification at 800оC and then HC covered with a layer up to 1% of masses. Use of waste of MQ containing 40–60% of quartz (SiO2) in composition with MC and with further modification of a surface (up to 1% of masses.) humic connections will allow receiving highly effective, universal and inexpensive sorbents for sewage treatment from heavy metals and other pollutants. The offered composite sorbents will allow to solve several ecologically important problems in a complex: to carry out effective purification of industrial sewage (machine and instrument-making, metallurgical, petrochemical and other enterprises) of heavy metals ions and to utilize waste of micaceous quartz processing of and brown coal extraction.

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Waste, micaceous quartzite, montmorillonite clays, humic connections, surface modifying, sewage treatment, heavy metals ions

Короткий адрес: https://sciup.org/142227529

IDR: 142227529   |   DOI: 10.15828/2075-8545-2019-11-1-106-116

Список литературы Research of effectiveness of natural and modified sorbents for wastewater treatment based on mica quartzite treatment waste

  • Voronov Yu.V., Alekseev E.V., Salomeev V.P., Pugachev E.A. Vodootvedenie [Water disposal]. Moscow, INFRA, 2007. 261 p. (In Russian).
  • Burenin V.V. Ochistka i obezvrezhivanie stochnyh vod promyshlennyh predpriyatiy [Cleaning and neutralization of sewage of the industrial enterprises]. Himicheskaya tekhnika [Chemical equipment]. 2009. no. 7. pp. 37–41. (In Russian).
  • Zhukov A.I., Mongajt I.L., Rodziller I.D. Metody ochistki proizvodstvennyh stochnyh vod: spravochnoe posobie [Methods of purification of production sewage: handbook]. Moscow, Strojizdat, 1977. 111 p. (In Russian).
  • Tuktarova I.O., Malikova T.Sh., Tuktarova I.F. Ocenka vozdejstviya na okruzhayushchuyu sredu i ekologicheskaya ekspertiza: uchebno-metodicheskoe posobie po provedeniyu prakticheskih zanyatij [Environmental impact assessment and environmental assessment: an educational and methodical grant on carrying out a practical training]. Ufa, UGUES, 2015. 71 p. (In Russian).
  • Ismagilov Z.R. Sovremennye problemy glubokoj pererabotki uglya i uglekhimii [Modern problems of deep processing of coal and coal chemistry]. Trudy Mezhdunarodnoj nauchno-prakticheskoj konferencii «Kompleksnyj podhod k ispol’zovaniyu i pererabotke uglya» [Works of the International scientific and practical conference «Integrated Approach to Use and Processing of Coal»]. Dushanbe. 2013. pp. 15–16. (In Russian).
  • Nazarov A.M., Latypova F.M., Araslanova L.Kh., Sal’manova E.R., Tuktarova I.O. Research of efficiency of natural and modified sorbents for purification of industrial sewage from heavy metal ions. Nanotehnologii v stroitel’stve = Nanotechnologies in Construction. 2018, Vol. 10, no. 5, pp. 125–143. DOI: dx.doi. org/10.15828/2075-8545-2018-10-5-125-143. (In Russian).
  • Latypova F.M., Araslanova L.Х., Garankov I.N., Smolova I.N. Adsorbcionnaya ochistka stochnyh vod na prirodnyh sorbentah [Adsorptive sewage treatment on natural sorbents]. Sbornik nauchnyh statej Vserossijskoj nauchno-prakticheskoj konferencii «Strategiya Respubliki Bashkortostan – 2030: prioritety ehkonomicheskogo rosta» [Collection of scientific articles of the All-Russian scientific and practical conference «The Strategy of the Republic of Bashkortostan – 2030: priorities of economic growth»]. Ufa: USPTU, 2017. pp. 189–191. (In Russian).
  • Izyumov Yu.A., Chernenko Yu.V. Ochistka stochnyh vod s pomoshch’yu promyshlennyh othodov [Sewage treatment by means of industrial wastes]. Sovershenstvovanie metodov gidravlicheskih raschetov vodopropusknyh i ochistnyh sooruzhenij [Improvement of methods of hydraulic calculations of water throughput and treatment facilities. Ecology of industrial production]. 2016. Vol. 1, no. 1 (42). pp. 106–112. (In Russian).
  • Stepanov S.V., Panfilova O.N., Abdugaffarova K.K. Doochistka stochnyh vod ot ionov tyazhelyh metallov novym sorbentom na osnove modificirovannyh glin [Removing heavy metal ions from wastewater in the process of tertiary treatment with a new sorbent based on modified clays]. Vodosnabzhenie i sanitarnaya tekhnika [Water supply and the sanitary equipment]. 2018. no. 1. pp. 46–50. (In Russian).
  • Vinogradov S.S. Ekologicheski bezopasnoe gal’vanicheskoe proizvodstvo [Ecologically safe galvanic production]. M.: Production and publishing enterprise «Globus», 1998. 302 p. (In Russian).
  • Godymchuk A.Yu. Tekhnologiya izgotovleniya silikatno-karbonatnyh sorbentov dlya ochistki vody ot kationitov tyazhelyh metallov: PhD thesis. [Manufacturing techniques of silicate and carbonate sorbents for water purification from cation exchangers of heavy metals: diss. … cand. tech. sci.]. Tomsk. 2003. 192 p. (In Russian).
  • Malkin P. Wastewater treatment from heavy metal ions using nanoactivated complexes of natural zeolite and diatomite. Nanotehnologii v stroitel’stve = Nanotechnologies in Construction. 2018, Vol. 10, no. 2, pp. 21–41. DOI: dx.doi. org/10.15828/2075- 8545-2018-10-2-21-41. (In Russian).
  • Rys’ev O.A., Shirokova Z.V. Sposob sorbcionnoj ochistki pit’evoj vody [Way of sorption cleaning of drinking water]. Patent RF 2074120 [Patent of the Russian Federation 2074120]. 1995. (In Russian).
  • Osadchenko I.M., Gorlov I.F., Spivak M.E., Dikusarov V.G. Sposob polucheniya sorbenta na mineral’noj osnove [Sposob of receiving a sorbent on a mineral basis]. Patent RF 2311955 [Patent of the Russian Federation 2311955]. 2007. (In Russian).
  • Greg S., Sing K. Adsorbciya, udel’naya poverhnost’, poristost’ [Adsorption, specific surface, porosity]. Moscow, Mir, 1984. 36 p. (In Russian).
  • Museev T.S., Soldatov K.V. Analiz sovremennyh sorbentov, na osnove materialov organicheskogo proiskhozhdeniya [The analysis of modern sorbents, on the basis of materials of organic origin]. Aktual’nye problemy gumanitarnyh i estestvennyh nauk [Current problems of humanitarian and natural sciences]. 2017. no. 1-1. pp. 69–73. (In Russian).
  • Latypova F.M., Araslanova L.H., Lukmanov I.I., Garankov I.N. Issledovanie adsorbcionnyh svojstv prirodnyh sorbentov dlya ochistki stochnyh vod [Study of adsorption properties of natural sorbents for wastewater treatment]. Materialy II Mezhdunarodnoj nauchno-prakticheskoj konferencii «Bulatovskie chteniya» [Materials II of the International scientific and practical conference «Bulatovsky Readings»]. Tom 5 [Vol. 5]. Krasnodar: «Izdatel’skij Dom – Yug». 2018. pp. 155–158. (In Russian).
  • Zhumamurat M.S., Ahmetova A.B. Vybor prirodnyh sorbentov dlya ochistki stochnyh vod [Choice of natural sorbents for sewage treatment]. Aktual’nye nauchnye issledovaniya v sovremennom mire [Relevant scientific research in the modern world]. 2017. no. 1–3 (21). pp. 116–125. (In Russian).
  • Stepanov S.V., Panfilova O.N. Analiz sovremennyh tekhnologij doochistki stochnyh vod ot ionov tyazhelyh metallov [The analysis of modern technologies of tertiary treatment of sewage from ions of heavy metals]. Tradicii i innovacii v stroitel’stve i arhitekture. Stroitel’nye tekhnologii: sbornik statej [Traditions and an innovation in construction and architecture. Construction technologies: collection of articles]. Samara: SGASU, 2015. pp. 282–287. (In Russian).
  • Dudina S.N. Modificirovanie sorbentov na osnove prirodnyh glinistyh materialov [The modification of sorbents based on natural clay materials]. Nauchnye vedomosti Belgorodskogo gosudarstvennogo universiteta. Seriya: Estestvennye nauki [Belgorod State University Scientific Bulletin. Series: Natural sciences] 2013. no. 24 (167). pp. 131–134. (In Russian).
  • Araslanova L.H., Biktasheva L.F., Tuktarova I.F., Bikbaeva E.M. Prirodnye sorbenty dlya ochistki stochnyh vod mashinostroitel’nyh predpriyatij [Natural sorbents for the purification of wastewater engineering enterprises] Devyataya Vserossijskaya konferenciya molodyh uchenyh i specialistov «Budushchee mashinostroeniya Rossii»: sbornik dokladov. [Ninth All-Russian conferences of young scientists and experts «The future of mechanical engineering of Russia»: collection of reports.]. Moscow, MSTU publishing house of N.E. Bauman, 2016. pp. 597–601. (In Russian).
  • Bikbaeva E.R., Smolova I.N., Tuktarova I.F. Prirodnye sorbenty dlya ochistki stochnyh vod ot tyazhelyh metallov [Natural sorbents for sewage treatment from heavy metals]. Trudy X Mezhdunarodnoj nauchno-prakticheskoj konferencii molodyh uchenyh «Aktual’nye problemy nauki i tekhniki» [Works X of the International scientific and practical conference of young scientists «Current problems of science and technology»]. Ufa, USPTU, 2017. pp. 192–193. (In Russian).
  • Popov A.I. Guminovye veshchestva: svojstva, stroenie, obrazovanie [Humic substances: properties, the building, education]. Pod red. E.I. Ermakova [Under editorship of E.I. Ermakov]. SPb., Publishing house SPb.: S.-Peterb. university. 2004. 325 p. (In Russian).
  • PNDF 14.1:2.50-96. Metodika vypolneniya izmerenij massovoj koncentracii obshchego zheleza v prirodnyh i stochnyh vodah fotometricheskim metodom s sul’fosalicilovoj kislotoj [A technique of performance of measurements of mass concentration of the general iron in natural and sewage by a photometric method with sulfosalicylic acid]. – Moscow, Gosstandart of Russia: Prod. standards, 2004. 16 p. (In Russian).
  • PNDF 14.1:2.52-96. Kolichestvennyj himicheskij analiz vod. Metodika vypolneniya izmerenij massovoj koncentracii ionov hroma v prirodnyh i stochnyh vodah fotometricheskim metodom s difenilkarbazidom [Quantitative chemical analysis of waters. A technique of performance of measurements of mass concentration of ions of chrome in natural and sewage by a photometric method with difenilkarbazidy]. Moscow, Gosstandart of Russia: Prod. standards, 2004. 10 p. (In Russian).
  • Garankov I.N., Salmanova E.R., Araslanova L.H., Nazarov A.M. Ispol’zovanie othodov dolomita v kachestve sorbentov tyazhelyh metallov [Use of waste of dolomite as sorbents of heavy metals]. Stat’i i tezisy VII Mezhdunarodnoj nauchno-tekhnicheskoj konferencii studentov, aspirantov i molodyh uchenyh «Vodosnabzhenie, vodootvedenie i sistemy zashchity okruzhayushchej sredy» [Articles and theses of the VII International scientific and technical conference of students, graduate students and young scientists «Water supply, water disposal and systems of environment protection»]. Ufa, USPTU, 2018. pp. 96–98. (In Russian).
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