Synthesis and study of 2-alkenyl(propargyl)thio-4,6- dimethylpyrimidine by gas chromatography-mass spectrometry
Автор: Shalkova E.N., Kim D.G., Frolova T.V., Fatykhov R.R.
Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry
Рубрика: Органическая химия
Статья в выпуске: 3 т.9, 2017 года.
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2-Alkenylthio-4,6-dimethylpyrimidine and 2 propargylthio-4,6-dimethylpyrimidine were synthesized by the interaction between 4,6-dimethyl-2-pyrimidinone hydrochloride and alkenyl halides and propargylbromide, respectively, in the presence of potassiumhydroxide. Main mass fragmentations routs for S-derivatives of 4,6-dimethyl-2-pyrimidinonewere revealed by gas chromatography-mass spectrometry analysis.
6-dimethyl-2-pyrimidinthionehydrochloride, 2-(4-chlorobut-2-enyl)thio-4, 6-dimethylpyrimidine, 2(4-pentenyl)thio-4, 2-(3-butene-1-yl)thio-4, 2-propargylthio-4, 2-prenylthio-4, 6dimethyl-lpyrimidine, 2-methallylthio-4, 2-allylthio-4, gas chromatography-mass spectrometry
Короткий адрес: https://sciup.org/147160393
IDR: 147160393 | DOI: 10.14529/chem170303
