Synthesis and structure of iodotris(tryphenylstibine)silver [(Ph 3Sb) 3AgI]
![Synthesis and structure of iodotris(tryphenylstibine)silver [(Ph 3Sb) 3AgI]](/file/picture/147160344/synthesis-and-structure-of-iodotris-tryphenylstibine-silver-ph-3sb-3agi.png "Synthesis and structure of iodotris(tryphenylstibine)silver [(Ph 3Sb) 3AgI]")
Автор: Sharutin V.V., Sharutina O.K., Senchurin V.S., Neudachina A.N., Andreev P.V.
Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry
Рубрика: Химия элементоорганических соединений
Статья в выпуске: 1 т.8, 2016 года.
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Interaction of silver iodide with triphenylstibine in dimethyl sulfoxide has led to the neutral complex iodotris(triphenylstibine)silver (1), whose structure has been established by X-ray diffraction analysis. The silver atom has distorted tetrahedral coordination. The angles SbAgSb and SbAgI equal 106.501(13)°, 109.644(13)°, 111.099(13)° и 103.063(13)°, 111.594(14)°, 114.337(14)°, the bond lengths Ag-Sb and Ag-I equal 2.7291(4), 2.7326(4), 2.8087(4) и 2.7600(4) Å.
Iodotris(triphenylstibine)silver, synthesis, structure, x-ray diffraction analysis
Короткий адрес: https://sciup.org/147160344
IDR: 147160344 | DOI: 10.14529/chem160107
Список литературы Synthesis and structure of iodotris(tryphenylstibine)silver [(Ph 3Sb) 3AgI]
- Effendy. Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXVIII. Synthesis and Structural Systematics of Some 1: 3 Adducts of Silver(I) Compounds with Triphenylstibine, , X = Cl, I, SCN, NCS, CN, ONO2/Effendy, J.D. Kildea, A.H. White//Aust. J. Chem. -1997. -V. 50, № 6. -P. 587-604.
- Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXXII† Synthesis, Spectroscopy and Structural Systematics of Some 1: 2 Binuclear Complexes of Silver(I) Halides with Triphenylstibine, , X = Cl, Br, I/G.A. Bowmaker, Effendy, E.N. Silva et al.//Aust. J. Chem. -1997. -V. 50, № 6. -P. 641-651.
- Bruker (2000) SMART. Bruker Molecular Analysis Research Tool, Versions 5.625 Bruker AXS, Madison, Wisconsin, USA.
- Bruker (2000) SAINTPlus Data Reduction and Correction Program Versions 6.02a, Bruker AXS, Madison, Wisconsin, USA.
- Sheldrick, G.M. A Short History of Shelx/G.M. Sheldrick//Acta Cryst. -2008. -V. A64, № 1. -P. 112-122.
- Бацанов, С.С. Атомные радиусы элементов/С.С. Бацанов//Журн. неорган. химии. -1991. -Т. 36, вып. 12. -С. 3015-3037.
- Ansell, G.B. Crystal Structure of 1:1 Complex between Silver Iodide and Morpholine/G.B. Ansell//J. Chem. Soc., Perkin Trans., II. -1976. -№ 1. -P. 104-106.
- Structure Analysis of Triaryl Derivatives of the Group V Elements. Crystal and Molecular Strycture of Tri-p-tolylantimony, C21H21Sb/A.N. Sobolev, I.P. Romm, V.K. Belskii et al.//J. Organomet. Chem. -1979. -V. 179, № 2. -P. 153-157.
