The oxidative-addition reactions of tri(meta-tolyl) antimony and tri(ortho-tolyl)antimony with 5-nitrofurfuraldoxime in the presence of peroxides. The molecular structures of 2-oxo-bis[(5- nitrofurfuraldoximato)tri(meta-tolyl)antimony] and 2-oxo-bis[(5-nitrofurfuraldoximato)tri(ortho- tolyl)antimony]
![The oxidative-addition reactions of tri(meta-tolyl) antimony and tri(ortho-tolyl)antimony with 5-nitrofurfuraldoxime in the presence of peroxides. The molecular structures of 2-oxo-bis[(5- nitrofurfuraldoximato)tri(meta-tolyl)antimony] and 2-oxo-bis[(5-nitrofurfuraldoximato)tri(ortho- tolyl)antimony]](/file/picture/147160389/the-oxidative-addition-reactions-of-tri-meta-tolyl-antimony-and-tri-ortho-tolyl.png "The oxidative-addition reactions of tri(meta-tolyl) antimony and tri(ortho-tolyl)antimony with 5-nitrofurfuraldoxime in the presence of peroxides. The molecular structures of 2-oxo-bis[(5- nitrofurfuraldoximato)tri(meta-tolyl)antimony] and 2-oxo-bis[(5-nitrofurfuraldoximato)tri(ortho- tolyl)antimony]")
Автор: Artemeva E.V., Makerova M.S., Sharutin V.V., Sharutina O.K.
Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry
Рубрика: Химия элементоорганических соединений
Статья в выпуске: 2 т.9, 2017 года.
Бесплатный доступ
The interaction of tri(meta-tolyl)antimony and tri(ortho-tolyl)antimony with 5-nitrofurfural oxime in the presence of an oxidizing agent (hydrogen peroxide or tert-butyl hydroperoxide) leads to the formation of bis(5-nitrofurfuraldoximato)tri(meta-tolyl)antimony (1), μ2-oxo-bis[(5-nitrofurfuraldoximato)tri(meta-tolyl)antimony] (2), bis(5-nitrofurfuraldoximato) tri(ortho-tolyl)antimony (3) and μ2-oxo-bis[(5-nitrofurfuraldoximato)tri(ortho-tolyl)antimony] (4). The molecular structures of complexes 2 and 4 have been determined by X-ray diffraction analysis.
Tri(m-tolyl)antimony, tri(o-tolyl)antimony, 5-nitrofurfuraldoxime, tert-butyl hydroperoxide, hydrogen peroxide, oxidation, bis(5-nitrofurfuraldoximato)tri(m-tolyl) antimony, μ2-oxo-bis[(5-nitrofurfuraldoximato)tri(m-tolyl)antimony], μ2-oxo-bis[(5-nitrofurfuraldoximato)tri(o-tolyl)antimony], molecular structures, x-ray diffraction analysis
Короткий адрес: https://sciup.org/147160389
IDR: 147160389 | DOI: 10.14529/chem170207
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