Влияние высокодисперсного порошка смеси Wc и TiC на свойства композиционных материалов
Автор: Чайка Татьяна Валерьевна, Гавриш Владимир Михайлович, Павленко Вячеслав Иванович, Черкащина Наталья Игоревна
Журнал: Нанотехнологии в строительстве: научный интернет-журнал @nanobuild
Рубрика: Применение нанотехнологий и наноматериалов в строительстве
Статья в выпуске: 1 т.15, 2023 года.
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Введение. Исследование направлено на изучение влияния высокодисперсного порошка смеси WC, TiC, полученного в результате рециклинга твердосплавных изделий группы ТК (титановольфрамовые сплавы), на изменение структурных и физико-механических свойств цементных материалов. Материалы и методы исследования. Порошок WC, TiC (размер частиц 20-150 нм, агломератов 300 нм - 1,5 мкм) добавляли в цементный раствор путем частичной замены цемента в различных концентрациях 0%, 1%, 2%, 3%, 4%, 5 % по массе. Основные физико-механические показатели цементной пасты и полученных цементных материалов изучали в соответствии со стандартными методиками, с учетом требований нормативной документации российских и зарубежных стандартов. Также были применены термокинетический, рентгенофазовый анализ, сканирующая электронная микроскопия с интегрированной системой энергодисперсионного анализа. Результаты и обсуждение. Установлено, что добавление высокодисперсного порошка WC, TiC в цементные материалы приводит к увеличению плотности, растекаемости теста, сокращению времени схватывания, снижению водопоглощения, пористости, повышению прочностных характеристик как в ранние, так и в более поздние сроки твердения. Добавление высокодисперсной добавки способствует более ранней гидратации. Структура цементного образца с добавлением порошка более плотная во все рассматриваемые сроки твердения по сравнению с контрольным образцом. Заключение. Полученные результаты исследования представляют важное значение для понимания механизмов действия высокодисперсных частиц WC, TiC на цементные материалы, что в дальнейшем может быть использовано для улучшения свойств композиционных материалов на основе цемента различных областей применений.
Композиты, добавка, высокодисперсный порошок, модифицирование, карбид вольфрама, карбид титана, прочность
Короткий адрес: https://sciup.org/142237350
IDR: 142237350 | DOI: 10.15828/2075-8545-2023-15-1-14-26
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