Study of the effect of additives on biodegradation of PVC materials
Автор: Mazitova A.K., Vikhareva I.N., Maskova A.R., Gareeva N.B., Shaikhullin I.R.
Журнал: Nanotechnologies in Construction: A Scientific Internet-Journal @nanobuild-en
Рубрика: Development of new polymer materials
Статья в выпуске: 2 Vol.12, 2020 года.
Бесплатный доступ
Modern operating conditions of polyvinyl chloride (PVC) materials impose increased requirements for the additives used. Intensification of processing and expansion of PVC application areas, as well as providing a wide variety of its performance characteristics, are associated to a large extent with the successful solution of the problem of creating effective plasticizers. Therefore, when developing formulations of PVC plasticates, it is important to obtain and select plasticizers that meet modern high requirements for operation and environmental safety. One of the modern approaches to creating materials that can be destroyed in natural conditions is based on the use of additives that increase the ability of polymer materials to biodegrade. This paper presents the results of developing a PVC composition with increased biodegradation. For this purpose, a mixture of plasticizers was used: dibutoxyethyl phthalate (DBOEP) with a degree of ethoxylation of 1.5 and dibutoxyethyl adipate (DBOEA) with a degree of ethoxylation of 1.5. The results of testing samples of obtained PVC compositions for biodegradation are presented. It is shown that partial replacement of a phthalate plasticizer with a non-toxic biodegradable dibutoxyethyl adipate makes it possible to obtain PVC compositions with increased biodegradation, while maintaining excellent performance properties.
Adipate plasticizer, biodegradation, ecological safety, phthalate plasticizer, polyvinyl chloride
Короткий адрес: https://sciup.org/142227422
IDR: 142227422 | DOI: 10.15828/2075-8545-2020-12-2-94-99
Список литературы Study of the effect of additives on biodegradation of PVC materials
- Ul’yanov V.M., Rybkin E.P., Gudkovich A.D., Pishin G.A. Polivinilkhlorid [Polyvinylchloride]. Moscow, Khimiya, 2000. 288 р. (In Russian).
- Fadina Yu.I. Analiz rossiiskogo rynka polimerov i dal’neishie puti ego razvitiya [Analysis of the Russian polymer market and its further development]. Biznes-obrazovanie v ekonomike znanii = Business Education in the Knowledge Economy. 2017, no. 1, рр. 99–101.
- Holden G., Kriheldorf H.R., Kuirk R.P. Termoelastoplasty [Thermoplastic Elastomers]. St. Petersburg, Profession, 2011. 720 p.
- Jakoby R. Marketing and sales in the Chemical Industry in Plastics and Rubbers. 2nd ed. New York, Wiley, 2002. 177 p.
- Pakharenko V.A., Pakharenko V.V., Yakovleva R.A. Plastmassy v stroitel’stve [Plastics in Construction]. St. Petersburg, Scientific foundations and technologies, 2010. 358 p. (In Russian).
- Mazitova A.K., Aminova G.K., Nafikova R.F., Deberdeev R.Ya. Osnovnye polivinilhloridnye kompozicii stroitel’nogo naznacheniya [Basic polyvinyl chloride compositions for construction purposes]. Ufa, 2013. 130 p. (In Russian).
- Schiller M. PVC Additives. Composition, properties, application. Germany, Munich, 2014. 400 p.
- Rahman M., Brazel C.S. The plasticizer market: An assessment of traditional plasticizers and research trends to meet new challenges. Prog. Polym. Sci. 2004, Vol. 29, no. 12, pp. 1223–1248.
- URL: https://www.plasticisers.org/applications/
- URL:http://www.mrcplast.ru/
- Wilkes C.E., Summers J.W., Daniels C.A., Berard M.T. PVC Handbook. Hanser Publications. 2005. 723 р.
- Godwin A.D. Plasticizers. Applied Plastics Engineering Handbook Elsevier, 2017. 784 p.
- Chanda M., Roy S.K. Plastics technology handbook. CRC Press, 2006. pp. 1–6.
- Wickson E.J., Grossman R.F. The development of compositions based on PVC. St.Petersburg, Scientific foundations and technologies, 2009. 608 p. (In Russian).
- Godwin A.D. Plasticizer selection and phthalate alternatives. Presented at Society of Plastic Engineers Vinyl Division Technical Conference. Vinyltec 2008. Chicago, 2008.
- Bolton D. Eastman Chemical Webinar Presentation. Suppliers going DEHP-free, it’s easier than you think. URL: https:// practicegreenhealth.
- European Commission Health & Consumer protection directorate-general, Directorate C-Scientific Opinions, C2. Opinion on Medical Devices Containing DEHP plasticized PVC. Neonates and Other Groups Possibly at Risk from DEHP Toxicity. 2002. Doc.SANCO/SCMPMD/2002/0010:final.
- Vasnev V.A. Biorazlagaemye polimery [Biodegradable Polymers]. Vysokomolek. Soed. B. = High Molecule. Connection B. 1997, Vol. 39, no. 12, pp. 2073–2086.
- Gogotov I.N. Biorazlagaemye polimery: svojstva, prakticheskoe ispol’zovanie, utilizaciya [Biodegradable polymers: properties, practical use, disposal]. Ekologiya i promyshlennost’ Rossii = Ecology and industry of Russia. 2007, pp. 16–19.
- Gu J.D., Ford T.E., Mitton D.B., Mitchel R. Microbial degradation and deterioration of Polymeric materials. Review. The Uhlig Corrosion Handbook. Wiley, New York, 2000, pp. 439–460.
- Shembel N.L., Chebotar A.M., Sagalaev G.V. Napolniteli polimernyh materialov [Fillers of polymeric materials]. Moscow, Knowledge, 1977. pp. 87–91.
- Sherieva M.L., Shustov G.B., Shetov R.A., Beshtoev B.Z., Kanametova I.K. Issledovanie smesej na osnove kukuruznogo krahmala i polietilena [The study of mixtures based on corn starch and polyethylene]. Materialy II Vserossijskoj nauchno-tekhnicheskoj konferencii «Novye polimernye kompozicionnye materialy» [Materials of the II All-Russian scientific and technical conference “New polymer composite materials”]. Nalchik, 2005, pp. 266–273.
- Chiellini F., Ferri M., Morelli A., Dipaola L., Latini G. Perspectives on alternatives to phthalate plasticized poly(vinyl chloride) in medical devices applications. Prog. Polym. Sci. 2013, Vol. 38, no. 7, pp. 1067–1088.
- Vieira M.G.A., Silva M.A.D., Santos L.O., Beppu M.M. Natural-based plasticizers and biopolymer films: A review. Eur. Polym. J. 2011, Vol. 47, pp. 254–263.
- Vijayendran B.R., Benecke H., Elhard J.D., McGinniss V.D., Ferris K.F. Environmentally Friendly Plasticizers for Polyvinyl Chloride (PVC). Resins Antec, Dallas, Texas, 2001, 604 p.
- Vikhareva I.N., Builova E.A., Gatiyatullina D.R., Arslanov V.R., Gilem’yanov D.A., Mazitova A.K. Sintez i svoistva slozhnykh efirov adipinovoi kisloty [Synthesis and properties of adipic acid esters]. Bashkirskii khimicheskii zhurnal = Bashkir chemical journal. 2019, Vol. 26, no. 2, рр. 33–36.
- Mazitova A.K., Vikhareva I.N., Aminova G.K., Timofeev A.A., Builova E.A., Distanov R.Sh. Issledovanie vliyaniya kolichestva dobavok na svoistva efirov adipinovoi kisloty [Investigation of the effect of the amount of additives on the properties of adipic acid esters]. Nanotechnologies in construction. 2019, Vol. 11, no. 4, рр. 437–446.
- Maskova A.R., Aminova G.K., Rolnik L.Z., Faizullina G.F., Mazitova A.K. Oxyalkylated alcohols phthalates. Nanotechnologies in Construction. 2019, Vol. 11, no. 1, pp. 52–71. DOI: 10.15828/2075-8545-2019-11-1-52-71.
- Ermolovich O.A., Makarevich A.V., Goncharova E.P., Vlasova G.M. Methods for Analyzing of Biodegrability of Polymeric Materials. Biotechnology in Russia. 2005, № 4, pp. 47–54.
- Shtilman M.I. Biodegradaciya polimerov [Biodegradation of polymers]. Zhurnal sibirskogo federal’nogo universiteta. Seriya: biologiya = Journal of the Siberian Federal University. Series: biology. 2015, Vol. 8, no. 2, pp. 113–130.
- Bakshitsky M.N. Dlitel’naya prochnost’ polimerov [Long lasting polymer strength]. Moscow, Chemistry, 1978. 312 p. (In Russian).
- Orekhov D.A., Vlasova G.M., Makarevich A.V., Pinchuk L.S. Biorazlagaemye plenki na osnove termoplastov [Biodegradable films based on thermoplastics]. Reports of the National Academy of Sciences of Belarus. 2000, Vol. 44, no. 6, pp. 100–103.
- Suvorova A.I. Biorazlagaemye sistemy: termodinamika, reologicheskie svojstva i biokorroziya [Biodegradable systems: thermodynamics, rheological properties and biocorrosion]. Vysokomolekulyarnye soedineniya = High-molecular compounds. 2008, Vol. 50, no. 7, pp. 1162–1171.
- Rybkina S.P., Pakharenko V. A., Shostak T. S., Pakharenko V.V. Osnovnye napravleniya v oblasti sozdaniya biorazlagaemyh termoplastov [The main directions in the field of creating biodegradable thermoplastics]. Plasticheskie massy = Plastics. 2008, no. 10, pp. 47–54.
