Process modelling and optimization of green lube oil synthesis

Process modelling and optimization of green lube oil synthesis

Автор: Owolabi Rasheed U., Usman Mohammed A., Oluwasola Oribayo, Samuel Ikuejawa T.

Журнал: Журнал Сибирского федерального университета. Серия: Техника и технологии @technologies-sfu

Статья в выпуске: 8 т.13, 2020 года.

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Modeling and optimization of trans-esterification of palm kernel oil (PKO) to trimethylolpropone ester (TMP ester- a bio-lubricant) via palm kernel oil methyl ester (PKOME-a biodiesel) synthesis were investigated. The central composite design (CCD) component of the response surface methodology (RSM) was adopted for the optimization of the process parameters, where temperature and weight ratio of PKOME to TMP were held constant at 130 °C and 3.9 : 1 respectively, to generate 20 experimental runs. Bio-lubricant yield was calculated for each experimental run. A quadratic-like model was generated that related the yield to the process parameters (Reaction time, Stirring Speed, and Catalyst concentration). The predicted and actual R2 value were 0.9856 and 0.9959 respectively, which indicate an excellent agreement between experimental and predicted bio-lubricant yield. The predicted maximum bio-lubricant yield was 98.11 % at reaction time of 99.9084 mins, stirring speed of 863.794 rpm, and catalyst concentration 0.84522 wt. %. The experimental value obtained under same conditions was 96.996 %. Physico-chemical analysis of the bio-lubricant synthesized at optimum conditions were found to be within the range of the ASTM standard for bio-lubricants.

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Modelling, optimization, trans-esterification, bio-lubricant

Короткий адрес: https://sciup.org/146281617

IDR: 146281617   |   DOI: 10.17516/1999-494X-0281

Список литературы Process modelling and optimization of green lube oil synthesis

  • Akhabue C.E. and Ogogo J.A. Modelling and optimization of transesterification of palm Kernel oil cat alysed by calcium oxide derived from hen Eggshell wastes, Ife Journal of Science, 2018, 20, no. 1.
  • Alamu O.J. Optimal Operating Conditions for the Production of Biodiesel from Palm Kernel Oil, unpublished Ph.D. thesis, Mechanical Engineering Department, Ladoke Akintola University of Technology, Ogbomoso, Nigeria, 2007.
  • Alang M.B. et al. Synthesis and Characterisation of a Biolubricant from Cameroon Palm Kernel Seed Oil Using a Locally Produced Base Catalyst from Plantain Peelings. Green and Sustainable Chemistry, 2018, 8, 275-287.
  • Amit Kumar Jain, Amit Suhane. Research Approach & Prospects of Non Edible Vegetable Oil as a Potential Resource for Biolubricant - A Review", Advanced Engineering and Applied Sciences: An International Journal, 2012. Available at: http://www.urpjournals.com.
  • Amit Suhane, Rehman A., Khaira H.K. Potential of Non Edible Vegetable Oils as an Alternative Lubricants in Automotive Applications, International Journal of Engineering Research and Applications (IJERA), 2012, 2, Issue 5, pp.1330-1335.
  • AMSOIL, Syntheic Oil Canada n.d, Side-by-side comparison of synthetic vs conventional Mineral/Petrolium oil, AMSOIL Syntheic Oil Canada, 2009, viewed April 12. Available at: http://www.worldsbestoil.ca/long-engine-life.php
  • Anastasi U., Sortino O., Cosentino S.L., Patanè C. Seed yield and oil quality of perennial castor bean in a Mediterranean environment, Int. J. Plant Prod., 2015, 9, 99-116.
  • Anjani K. Castor genetic resources: A primary gene pool for exploitation, Indust. Crops Prod., 2012, 35(1), 1-14.
  • Azeez O.S. Production of biodiesel from palm kernel oil using FeO promotedsNaoH catalyst through transesterification, Journal of Applied Chemical Science International, 2016, 6(1), 40-44. ISSN: 2395-3705 (P), ISSN: 2395-3713 (O). International Knowledge Press.
  • Banerji A.R., Chowdhury G., Misra G., Sudarsanam S.C., Varma G.S., Srivastava G.S. Jatropha seed oil for energy, Biomass, 1985, 8, 277-282.
  • Basha S.A., Raja Gopal K., Jebaraj S. A review on biodiesel production, combustion, emissions and performance, Renew. Sustain. Energy Rev, 2009, 13, 1628-1634.
  • Bilal S., Mohammed-Dabo I.A., Nuhu M., Kasim S.A., Almustapha I.H. and Yamusa Y.A. Production of biolubricant from Jatropha curcas seed oil, Journal of Chemical Engineering and Materials Science, 2013. ISSN 2141-6605.
  • Bouflet A., Duteurte P., Airard P., et al. A challenge for the lubricant industries, Petrol Technol, 1991, 362, 65-79.
  • Chilingarian G.V. and Vorabutr P. Drilling and Drilling Fluids, 1983.
  • Da Silva J.A.C., Soares V.F., Fernandez-Lafuente R., Habert A.C., Freire D.M.G. J. Mol. Catal. B: Enzym., 2015, 122, p. 323-329.
  • Demirbas A. Biofuels securing the planet's future energy needs. Energy Convers. Manage, 2009, 50, 2239-2249.
  • Dosunmu A. and Joshua O. Development of environmentally friendly oil based mud using Palm-oil and groundnut-oil, 34th Annual SPE International Conference and Exhibition. Calabar: Society of Petroleum Engineers, 2010, pp. 1-9.
  • Dunford N.T. Food and Industrial Bioproducts and Bioprocessing. John Wiley & Sons, 2012.
  • Dwight Smith & Bob Frazier Archives, The Benefits of Bio-Based Lubricants, May, 2010. Available at: www.gearsolutions.com.
  • Environmentally Preferable Purchasing Fact Sheet. Biolubricant. Department of Ecology, State of Washington, 2011, Publication No. 11-04-004.
  • Freedman B., Pryde E.H. and Mounts T.L. Variables affecting the yield of fatty esters from transesterified vegetable oils, Journal of American Oil Chemists Society, 1984, 61(1), 1638.
  • Gainer G.C., Luck R.M. Modified Castor Oil Lubricant for Refrigerator Systems Employing Halocarbon Refrigerants, 1979.
  • Ghazi T.I., Gunam Resul M.F.M., Idris A. Production of an Improved Biobased Lubricant from Jatropha curcas as Renewable Source. Proceedings of Third International Symposium on Energy from Biomass and Waste, by CISA, Environmental Sanitary Engineering Centre (Venice) Italy, 2010.
  • Givens W. Fuels and Lubricants Handbook: Technology, Properties, Performance, and Testing. G. Totten ed. et al. ASTM International, 2003, p. 373, 0-8031-2096-6.
  • ISBN: 0803120966
  • Haas M.J. Improving the economics of biodiesel production through the use of low value lipids as feedstocks: Vegetable oil soapstock. Fuel Process Technol., 2005, 86, 1087-1096.
  • Hassan A.B., Abolarin M.S., Nasir A. and Ratchel U. Investigation on the Use of Palm Olein as Lubrication Oil. Leonardo Electronic Journal of Practices and Technologies, 2006, 5(8), 1-8.
  • Heinz P.B. Practical Lubrication for Industrial Facilities. Fairmont Press, 2009.
  • Helene M. Biolubricants, technical and market survey, NOVAK SURVEY, 2007, 2.
  • Hong D.-Y., Blackmore S. Plants of China: A Companion to the Flora of China. Cambridge University Press, 2015.
  • Honory L. Biodegradable/biobased lubricants and greases. Machinary Lubrication, 2010.
  • IENICA. Biolubricants: Market Data Sheet, IENICA, 2009, viewed April 12. Available at: http://www.ienica.net/marketdatasheets/biolubricantsmds.pdf
  • Ioan S. On the future of biodegradable vegetable lubricants used for industrial tribo systems, Gal I Fascicie, 2002, VIII, 1221-4590.
  • Jacques D., Briant J., Hipeaux J.-C. Lubricant Properties, Analysis and Testing‘, 1997, pp. 107-287. 2-7108-0746-7.
  • ISBN: 2710807467
  • Jumat S., Nadia S., Emad Y. Biolubricants: Raw materials, chemical modifications and environmental benefits, Eur. J. Lipid Sci. Technol., 2010, 112, 519-530.
  • Kamalakar K., Mahesh G., Prasad R.B., Karuna M.S. J. Oleo Sci., 2015, 64(12), 1283-1295.
  • Kazeem O., Taiwo O., Kazeem A., et al. Determination of some physical properties of castor (Ricirus communis) oil. Int. J. Sci. Eng. Technol., 2014, 3(12), 1503-1508.
  • Lansdown A.R. Lubrication and lubricant selection: a practical guide. New York, ASME Press, 2004.
  • Lashof D.A. and Ahuja D.R. Relative Contribution of Greenhouse Gases Emissions to Global Warming, Nature, 1990, 344, 529-531.
  • Lou Honary A.T. Performance of biofuels and biolubricant, Biobased Industry Outlook Conference, National Ag-Based Lubricants Center University of Northern Iowa, 2008.
  • Mang T., Lingg G., Mang I.T., Dresel W. Base oils, lubricants and lubrication, 2007, 34-35.
  • Martínez G., Sánchez N., Encinar J.M., González J.F. Biomass Bioenerg., 2014, 63, 22-32.
  • Meher L.C., Sagar V.D. Nnik, S.N. Technical aspects of biodiesel production by transesterification - a review, Renewable and sustainable Energy Review, 2006, 10, 248-268.
  • Miao X., Wu Q. Biodiesel production from hetrerotrophic microalgal oil. Bioresour. Technol., 2006, 97, 841-846.
  • Mohammed Modu Aji, Shettima Abba Kyari and Gideon Zoaka. Comparative studies between bio lubricants from jatropha oil, neem oil and mineral lubricant (engen super 20w/50), Applied Research Journal, 2015, 1(4), pp. 252-257.
  • Musa J.J. Evaluation of the Lubricating Properties of Palm Kernel Oil. Leonardo Electronic Journal of Practices and Technologies, 2009. ISSN 1583-1078.
  • Musa U. et al. Evaluation of Oxidation Storage Stability of Biodiesel - Petrodiesel Blends. Nigerian Journal of Solar Energy, 2016, 27.
  • Nagendramma P., Kaul S. Renew. Sust. Energ. Rev., 2012, 16, 764-774.
  • Novel Methodology for the Synthesis of Acyloxy Castor Polyol Esters: Low Pour Point Lubricant Base Stocks.
  • Obata J.C. Potentials of non-edible Abrus precatorius seed oil towards biodiesel production. African journal of biotechnology, full length research paper, 2014.
  • Onuh C.Y., Dosunmu A., Anawe P.A.L., Efeovbokhan V., Adebisi A. Transesterification of Non-Edible Vegetable Oil for Lubricant Applications in Water-Based Mud: A Review International Journal of Applied Engineering Research, 2017, 12(18), 7397-7401. ISSN 0973-4562.
  • Pantzaris T.P and Mohammed J.A. Palm Kernel oil article. Palm Oil Research Institute of Malaysia (PORIM), 2000.
  • Parsons G.M. Biodiesel and Engine Lubrication. Part 2, Califonia, Chevron Products Company, San Ramon, CA, 2007.
  • Persson B. Historical Note, Sliding friction physical principles and application. Germany: Springer-Verlag, 2000.
  • Placek D. Synthetics, Mineral Oils and Bio-based Lubricants, L. Rudnick ed., CRC Press, 2006, p. 519. 1-57444-723-8.
  • ISBN: 1574447238
  • Rahul G., Karmarkar A.S. Emerging trends and benefits of biolubricant. Chem Tech Foundation, 2013. Available at: http://www.chemtech-online.com/CP/rahul_july12.html
  • Refaat A.A. Different techniques for the production of biodiesel from waste vegetable oil. Int. J. Environ. Sci. Technol., 2010, 7(1), 183-213.
  • Reglitzky A., Kruntt Schneider H. The chances of exhaust emission reduction through conventional and alternative fuels. Deutsche Shell AG, 1992.
  • Rudnick L.R. Automotives Gear Lubricants, J.l of Chemistry and Technology, 2006, 425-440.
  • Sahoo D., Jena K.S., Rout P.K., Rao Y.R. Characteristics of Simarouba glauca seeds and fat of Orissa origin. J. Food Sci. Technol., 2002, 39(5), 552-555.
  • Sahoo P.K., Das L.M., Babu M.K.G., Naik S.N. Biodiesel development from high acid value polanga seed oil and performance evaluation in CI engine. Fuel, 2007, 86, 448-454.
  • Salimon J., Noor D.A.M., Nazrizawati A.T., Firdaus M.M., Noraishah A. Fatty acid composition and physicochemical properties of Malaysian castor bean Ricinus communis, L. seed oil. Sains Malays, 2010, 39(5), 761-764.
  • Salimon J., Salih N. and Yousif E. Biolubricants: Raw materials, chemical modifications and environmental benefits, European Journal of Lipid Science and Technology, 2010, 112(5), 519-530.
  • Scholz V., da Silva J.N. Biomass Bioenerg., 2008, 32, 95-100.
  • Sevim Z., Brajendra E., Sharma K., Perez J.M. Oxidation and low temperature stability of vegetable oil-based lubricants, Industrial Crops and Products, 2006, 24, 292-299.
  • Shah S., Sharma A., Gupta M.N. Extraction of oil from Jatropha curcas L. seed kernels by enzyme assisted three phase partitioning. Ind. Crops Prod., 2004, 20, 275-279.
  • Shahid E.M., Jamal J. Production of biodiesel: a technical review. Renew. Sustain. Energy Rev., 2011, 15(9), 4732-4745.
  • Sharma B.K., Adhvaryu A., Liu Z. and Erhan S.Z. Chemical modification of vegetable oils for lubricant applications. J. of the American Oil Chemists' Society, 2006, 83(2), 129-136.
  • Singh C.P. and Chhibber V.K. Research Article Chemical Modification in Karanja, Oil for Biolubricant Industrial, 2013. 3(3), 117-122.
  • Thomas A. Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA; 2000. Fats and fatty oils.
  • Wagner H., Luther R., Mang T. Lubricant base fluids based on renewable raw materials. Their catalytic manufacture and modification. Appl. Catal. A: Gen., 2001, 221, 429-442.
  • Willing A. Lubricants based on renewable resource - an environmentally compatible alternative to mineral oil products, Chemosphere, 2001, 43, 89-98.
  • Yang C.Y., Li Z.F.B., Long Y.F. Review and prospects of Jatropha biodiesel industry in China. Renew, Sustain. Energy Rev., 2012, 16, 2178-219.
  • Zheng S., Kates, M., Dube M.A. and McLean D.D. Acid-catalyzed production of biodiesel from waste frying oil, Biomass & Bioenergy, 2006, 30, 267-272.
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