Статьи журнала - Siberian Aerospace Journal
Все статьи: 387
Interaction of magnetic and dielectric subsystes in a bismuth nodymic ferrite-granate
Статья научная
Bismuth-substituted ferrite garnets possess magneto-optical (MO) properties and are used as spatial light modulators and indicators. The paper studies the influence of magnetic and electric fields on the structural characteristics of thin epitaxial films of bismuth-neodymium ferrite garnet (Bi: NIG) deposited on glass and gallium gadolinium garnet (GGG) substrates. Dynamic properties of polarization, relaxation in a magnetic and electric field are considered, which is an important task for getting a deep insight into the mechanisms of electromagnetic phenomena in solids. Dependence of the magnetostriction coefficient on the magnetic field and dependence of a relative change in the length of the film on the electric field at different temperatures are obtained. A change in the sign of magnetostriction constants with respect to temperature was found. The electric polarization in a periodically applied electric field of 400 V / cm with a frequency of 10 MHz is determined for various magnetic field orientations of 12 kOe and in the absence of a magnetic field. Anisotropy of polarization in a magnetic field and a functional dependence of the polarization relaxation on time are found. These materials can be used as sensors of the magnetic field in a spacecraft.
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Статья научная
Many strategically important sectors of the domestic industry are at the stage of transition to an investment approach to asset management. One of these industries is hydropower, where the current maintenance planning system needs new methods to deliver more efficient results. In general, the planning system for the main equipment (technical impact system) maintenance and repair can be formulated as a scheduling problem. The ant algorithm is of great interest from the point of view of solving the scheduling technical impact problem. Based on the specifics of planning, implementation and factors affecting the maintenance process, a modification of the ant algorithm is proposed. The mathematical description is a methodology for calculating parameters, basic elements of the graph, optimization criteria and constraints. A preparatory stage was also introduced into the solution algorithm, which determines the initial state of the equipment at the vertex K0. The functional model of the technical impact planning process presented in the article can be used to develop a software package within the framework of an innovative approach to asset management for hydropower companies.
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Статья научная
One of the most effective tools of remote sensing and visualization of underwater surfaces and objects are acoustic devices, in particular side-scan sonars (SSSs). Recently, largely due to the emergence of affordable devices, the geography and scope of application of SSSs has been significantly expanded. Meanwhile, despite certain progress achieved in terms of improving and minimizing the SSS hardware, the software used remains, in general, at a basic level, providing the operator mainly with a simple tool for visualizing benthic environments and data recording for further post-processing. Existing experience in SSS exploitation reveals that the key problem of interpreting acoustic images lies in the physical peculiarities of their acquisition. Arguably, attempts to implement methods of automated interpretation of optical images have no perspective. Hence, the objective of this paper is to provide a theoretical and practical background of SSS data interpretation and processing with the objective of further automation of this process. Taking into account the operating conditions of the SSS, in particular the vast areas of water areas - search zones, this problem is one of the key ones for SSS operators. The problem of automating data processing is directly related to the problem of interpreting remote sensing data, including satellite images, geometric distortion of images caused by the physical characteristics of the device and its operating environment, as well as referencing the obtained data to the satellite coordinate system.
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Статья научная
The relevance of the study is due to the need to improve the reliability and durability of steam turbines, which are widely used in the energy industry. One of the critical factors affecting the performance of turbines is the occurrence and development of cracks in the blades, which can lead to their destruction and emergency situations. This type of defects can significantly change the dynamic characteristics of a structure, reducing its life and increasing the likelihood of failure. Therefore, analyzing the effect of cracks on the vibration parameters and strength of blades is an important task for predicting their reliability and developing diagnostic methods. This article examines the effect of cracks on the dynamic and strength characteristics of steam turbine blades. The object of the study is a working wheel made of 304 stainless steel. The finite element model in the ANSYS Workbench environment was used for the analysis. The natural frequencies and vibration mode of the blades at different angular speeds of rotation, as well as the effect of cracks of various lengths on the dynamic characteristics of the structure, are investigated. The analysis results show that the presence of a defect leads to a decrease in natural oscillation frequencies, especially for low-frequency forms of bending vibrations. In addition, the effect of crack growth on the durability of the blades and the entire working wheel has been studied. It has been found that increasing the crack length significantly reduces the life of the blades, and the durability of the working wheel decreases more slowly due to the interaction of the blades with each other. The obtained results can be used in the development of methods for diagnosing and predicting the life of turbomachines, as well as to optimize their design in order to increase operational reliability.
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Статья научная
High-precision and reliable inspection of thermal deformations is necessary in terms of simulating the effects of space in the ground-based experimental processing of antennas and mirror systems of spacecrafts. Inspection of objects up to 1.5 m in size is considered in the paper. In practice, it can reach sizes up to 10 m. Requirements for thermal deformation are in range of 10–200 micrometers. The deformable surface is rough (Ra » λoptic). The measurement error, however, should not exceed ± 1 micron. The electronic speckle pattern interferometry (ESPI) method is the most suitable for solving this problem. The method allows to inspection objects with a randomly inhomogeneous surface. The method assumes that it is necessary to calculate the wave phase values from the recorded picture by the digital matrix. It is the phase that contains information about the deformation, and the spatial phase shift method is used to calculate it. One of the measuring systems based on this method is the measuring system PulsESPI (Carl Zeiss Optotechnik GmbH production, Germany). It has a high sensitivity which is about 50 nm. However, this measuring system is designed for single measurements. In this regard, an additional software module for processing and visualization the result of a series of several hundred measurements has been developed. The experimental test bench with a test object has been developed to research the metrological characteristics of the PulsESPI system in accordance with thermal deformations measurements (multiple determinations). The PulsESPI system and the Renishaw XL-80 interferometer introduced into register of measuring instrumentation of Russian Federation were located on different sides of the object 1.5 m in size. As a result of measuring the surface displacement measured by the Renishaw XL-80 interferometer and its corresponding point from the PulsESPI system deformation map are compared. Three types of tests were carried out at the developed bench. The root-mean-square deviation of single measurements was no more than ± 0.2 μm. Error was no more than ± 1 μm when the series of measurements was conducted in which a total strain of 200 μm was obtained. The results obtained suggest the possibility of using this system for high-precision inspection of thermal deformations of large objects.
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Статья научная
The object of the study is a cylindrical mesh shell without a regular structure covering, made of carbon fiber composite material. A distinctive feature of this class of structures is the intersection of families of annular and spiral ribs. Mesh shells are used as power elements of spacecraft, therefore, when designing them, the main re-quirements are a reduction in the mass of the structure, high strength and stiffness characteristics. The re-duction of the shell mass is achieved by varying and selecting the structural and geometric parameters of the ribs. The article considers a set of mesh cylindrical structures of fixed mass. The authors have developed and presented an algorithm for calculating the number of elements of a regular rib structure and calculating the values of geometric parameters of elements of rib families. Two approaches to the formation of rib sys-tems are considered: by changing the heights or thicknesses of the rib structure. A macro has been developed for modeling parametric discrete models of such rib structures in the An-sys Mechanical APD software package. When constructing discrete grid models, a one-dimensional two-node finite element BEAM4 was used. The model was rigidly attached at the nodes along the lower edge, a load was applied to the nodes of the upper edge. Two types of loading were considered. The “non-flight” mode was determined by the axial loading of the shell evenly distributed along the upper edge. Flight mode – additionally took into account the applied moment. The displacement and deformation fields were calculated numerically in the ANSYS finite element package. The article presents the results of a study of the effect of the density of the rib structure on the stability of mesh shells under static axial loading, natural frequencies and waveforms. It is shown that with increasing density, the rib structure becomes thinner. At the same time, the critical load decreases, the values of the natural frequencies of the shells decrease, and the number of waves in the forms increases. The influence of approaches to the modeling of rib structures on the results of numerical calculations is noted.
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Статья научная
We have considered the issues of ensuring the resistance of high-voltage solar battery (SB) of spacecraft to the effects of secondary arc discharges. Research in this area has been going on for more than 50 years, but the answer to all the questions has not yet been found. First of all, this is due to the complexity of the electrophysical processes occurring on the surface of the spacecraft in space and in laboratory conditions. The second reason is the random nature of secondary vacuum arc discharges, which requires the use of special test methods to confirm the effectiveness and reliability of selected design and technological solutions. Tests in conditions close to full-scale conditions do not allow us to solve this problem. We have given a retrospective review of publications on the physical features of secondary arcs arising on SB of spacecraft, the mechanisms of their initiation, experimental research and testing methods. We paid considerable attention to the issues of the occurrence of secondary arc discharges SB of the spacecraft in the conditions of ionospheric plasma and plasma generated by electric propulsion thrusters. We have shown that despite the large amount of accumulated data and knowledge, the transition from low-voltage SB to high-voltage SB remains a difficult scientific and technical problem, which requires additional research to solve. In addition, it is already necessary to start training personnel who possess a wide range of knowledge and are able to work on this topic. To do this, it seems advisable to organize sectoral research, as well as the allocation of targeted funds for the training of highly qualified specialists and their independent research. This approach will make it possible to solve the problem of creating high-voltage SB in the shortest possible time and prepare personnel for the development of this technology.
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Статья научная
The relevance of the work is explained by the significant problems of the modern aerospace industry, mechanical engineering, energy, mining, processing and other industries in the disposal of waste products made of composite materials and products based on composites of various functional purposes (carbon fiber, fiberglass, metalceramic and cast glass reinforced). The aim of the work is to increase the efficiency of processes for obtaining micron fractions of composite materials waste through the use of an upgraded roller crushershredder design. Computational and experimental studies have substantiated the possibility of increasing the efficiency of waste recycling of composite materials due to their gradual (step-by-step) disintegration. Based on analytical calculations and finite element analysis methods, a kinematic scheme, layout and design of an up-graded prefabricated roller crusher-shredder with working bodies (discs) in the form of an equiaxed contour – a Relo triangle – have been developed. The new design implements a more complex system of forces (compression, friction, alternating cyclic loads) compared to analogues, which makes it possible to increase the speed and productivity of the crushing process. The process of cutting the material using the “rotating scissors” mechanism is implemented between adjacent counter knives of the PK profile, which also contributes to more intensive grinding of the material (especially when processing lamellar or long fragments of waste). The original location and inconsistency of the contact points of the oncoming profiles, the gap between the discs during their rotation creates a rolling effect due to the reciprocating movement of the crushed material, which reduces the risk of jamming and increases the throughput of the grinding rolls and the intensity of the disintegration processes. In order to determine the best performance in terms of the size of the working bodies of the crusher, the gap between them when grinding materials with different sizes and properties, kinematic models were created to simulate the grinding processes and conduct a numerical experiment using finite element analysis methods. It is shown that due to the effective combina-tion of various fracture mechanisms (abrasion, crushing, cutting, alternating loads), the intensity of deformation processes and specific loads on the material increases, but the stresses on the working surfaces of the crusher vary in the range of 430–580 MPa, the safety margin of the working bodies increases to 0.43–0.65, which is a prerequisite for increasing the service life of the workers. grinding elements. The results of calculations using new methods and kinematic schemes show that the design of the upgraded prefabricated roller crusher with working bodies in the form of a Relo triangle has an increased resultant speed (by 30 %) and productivity is almost 2 times higher than the prototype with cylindrical rolls (with the same or comparable sizes of working bodies, kinematic parameters in terms of rotation speed and drive power). Design and technological preparation were carried out and a prototype of the installation for experimental studies was made, which confirmed a good agreement between the calculated and experimental data on the size of the gap, the speed and productivity of the crushing and crushing process.
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Kinematic model for manipulator robot control based on neural networks
Статья научная
In this paper, we consider the problem of controlling robotic manipula-tors based on trained artificial neural networks. It is based on the tasks of positioning manipulators, depending on the coordinates of the target point in Cartesian space. The direct and inverse kinematics problems have different methods, techniques, and algorithms for solving them. The authors propose calculating the coordinates of the manipulators, i.e. solving the tasks of the direct and inverse kinematics problems us-ing a trained neural networks based on the created kinematic model of the robot ma-nipulator. The mathematical model provides calculated data for neural networks training and is based on the Denavit–Hartenberg representation (DH representation), which allows us to obtain a homogeneous transformation matrix with a dimension of 4 x 4 describing the position of the coordinate system of each link relative to the coor-dinate system of the previous link. The kinematic model of the robot is implemented in the Matlab program using the Robotics System Toolbox. To do this, a function has been created that sets the structure of the manipulator and its parameters using the DH representation. Experimental studies of the model and various types of neural networks have been conducted, and appropriate algorithms and programs have been written for all processes. The conducted experimental studies allow us to judge the possibility of using the developed methods for solving kinematic problems of multi-link manipulators based on neural networks. The use of this approach is also relevant in aerospace for manipulator control in production and in space.
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Laboratory separator of bulk materials
Статья научная
New materials for spacecraft radiation screens engineering require a fine classification of powder materials by particle size. The article concerns the construction of powder materials laboratory separator. This type of material separation is related to gravity methods. The Moseley laboratory separator serves as the prototype of the construction with table longitudinal shaking and diametrical vibrations by means of buffers during the separation process. The unbalanced oscillator yields deck separation surface harmonic vibrations in all directions. The unbalanced oscillator DC motor voltage control gradually alters the vibration frequency and supports finer separation of the material. A power pipe enables to conduct perpetual separation process. In prototype, in contrast, up to 100 g weight is processed for up to 5 minutes. To improve the materials fine and small classes separation efficiency, riffles are made on the separation surface, which determine the places of concentration of material particles. As a result of the conducted researches for elimination of the secondary circulation flows, a system of diametrical reefing is worked out: the riffle is approximately equal to the maximum particle size of the separated material and is equal to 0.2 mm in this construction; the distance between riffles is equal to 50 mm, the tilt angle is 80 degrees relative to the deck longitudinal side. The particle motion depends on the inclination angle of the separation surface. Large particles move upwards at angles of up to 5 degrees, and downwards at angles higher than 5 degrees. Vibration frequency and amplitude alteration, as well as adjusting the inclination angle of separation surface enables to move and adjust the speed of different properties and sizes of test material. The laboratory separator work is based on the physical effects, which enable to vary the location of the power pipe. This fact allows the construction to be adapted to a variety of specific conditions and expands the construction sphere. The separator construction is simple for production and operation, and can be quickly reconfigured if necessary. The separator portability allows it to be transported.
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Laser processing of titanium alloys to increase the strength of adhesive joint with cfrp
Статья научная
Titanium alloys are hard-to-bond materials due to the fact that a thin oxide film is always present on their surface, which prevents the formation of interatomic and intermolecular bonds between the adhesive and the substrate. In the load-bearing structures of spacecraft (SC), an adhesive bond between a titanium alloy and a composite material is often used. But the strength of such knots is relatively small compared to the mechanical connection. The purpose of this work is to increase the strength of the adhesive joint, due to laser processing of the working surface of the titanium alloy for gluing. Texturing of the surface of the tita-nium alloy OT-4 was carried out on an ytterbium pulsed fiber laser in 4 processing modes. The treated sur-face was glued with KMU-4 carbon fiber over an area of 300 mm2 using a VK-9 three-component adhesive. The adhesive strength test was carried out on a Eurotest T-50 tensile tester. The test showed that the strength of the laser-treated samples increased by more than 80% relative to the average value of mechan-ical grinding. The highest value of shear strength was shown by samples with laser processing No. 1 and No. 3. This is due to the greatest increase in the area of bonding of the surface, as well as the mechanical locking of the adhesive in the microrelief of the structure. The increase in shear strength caused by laser surface treatment is a mixed effect of increasing surface area, mechanically locking the adhesive, and changing the surface chemistry. The chemical composition of the surface structure under the influence of laser scanning is gradually transformed from Ti and Ti2O3 to crystalline TiO2. The nature of the destruc-tion of the adhesive joint in the samples with laser processing is predominantly cohesive, but samples with the destruction of the carbon fiber material were also observed, that is, the shear stress in the composite material exceeded the adhesive strength. The effect of pretreatment of the composite material on the strength of the adhesive joint was not considered in this work.
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Library of mathematical functions with parallelism at the operational level in the Pythagor language
Статья научная
At present, developed tools and libraries have been designed for imperative and functional programming languages that provide parallelism through processes or threads. There are other alternative approaches to the organization of parallel computing, one of which is implemented in Pythagor – the language of functional-streaming parallel programming, and involves parallelism at the level of operations. The tools of the Pythagor programming language are actively developing, and the repository of predefined functions is expanding. Many mathematical functions have been designed to provide a developer with no less functionality than the math library math.h of the C programming language. A large part of the mathematical functions have been implemented using the Maclaurin’s series. It is both used as an approach of faster and less accurate calculations, in which a predetermined number of elements of the series is calculated without cycles and recursions with the substitution of pre-calculated coefficients in the function code, and as an approach of less rapid and more accurate calculations, in which the elements of the series are calculated dynamically until the desired accuracy is achieved. The development of a library of mathematical functions of a programming language is an applied algorithmic task already implemented in one way or another for a number of existing programming languages. But in many languages, the implementation of algorithms for mathematical functions is hidden from the user, while modern tools of the Pythagor language support an open repository of functions. Additional interest is the possibility of parallelism at the level of operations in the calculation of mathematical formulas in the Pythagor language.
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Статья научная
In this work, an analytical determination of the local heat transfer coefficient in the planes of rotation of gas turbines is carried out using an affine-like model for the distribution of temperature and dynamic spatial boundary layers with a convective component (at Pr < 1). The method of analytical study used in the work led to results close to the experimental values. The problem of determining the thickness of the energy loss is solved using the integral relation of the energy equation of the temperature spatial boundary layer, which makes it possible to integrate the necessary curvature over the surface. The law of heat transfer of the turbulent boundary layer for the rotational motion of the flow and motion according to the law of “solid body” is expressed. Equations are obtained for determining the local heat transfer coefficient by the Stanton criterion for various external flow laws for a power-law velocity distribution in the boundary layer according to the affine-like model of the temperature boundary layer. Heat transfer coefficients correlate with sufficient accuracy with experimental data and dependencies published by other authors: J. M. Owen, L. A. Dorfman, I. V. Shevchuk. The deviation of the results obtained from the dependence of the model with a convective component and with affinity-like profiles do not have statistically significant differences. The obtained results of the study and their comparison with the results of other authors showed that they are suitable for engineering calculations and analysis of the impact of local heat transfer coefficients on high-temperature units of a turbopump unit.
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Local stability of an elastic beam in a medium with constant resistance
Статья научная
This article deals with the analysis of the deformed shape of local stability loss of a reinforced flexible beam, occurring due to constrained expansion during heating. The multiple elastic supports of the beam modeled as an elastic medium, which provides constant resistance to both longitudinal and transverse displacements of the rod. The infinitely long beam divided into a buckling region and an adjacent region under compression. The lengths of these regions are unknown and should be determined during the solution process. A part of the potential energy accumulated during compression is expended on the work of internal forces during bending deformation following the loss of stability. This leads to a reduction in the magnitude of the compressive force in the buckled region. The problem of determining the displacement functions and the critical value of the safe heating temperature is formulated as a system of nonlinear differential equations concerning the deformations in the regions of the flexible beam. The solution obtained using the finite difference method, which transforms a system of differential equations into a system of linear algebraic equations. This system takes the closed form with boundary conditions and transversality conditions. A sufficient number of grid nodes for constructing the difference scheme determined through an iterative procedure that compares two adjacent solutions. The criterion for comparison of solutions is a tuple of areas under the graphs of the sought functions, which are calculated through numerical integration using the trapezoidal rule. The obtained final solution compared with the classical solution to the stability problem of an evenly loaded beam, which does not take into account longitudinal displacements. Additionally, it is contrasted with the known solution in the field of operation of continuously welded railway tracks, which also disregards resistance to longitudinal displacements in the buckled region. The refined results obtained by the proposed modified method for calculation of the parameters of the deformed shape of a flexible beam is important for monitoring the pre-critical state of the modelling system.
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Low-energy Earth – Moon – Earth flight trajectory design using optimization procedures
Статья научная
The problem of designing a low-energy Earth Moon Earth spacecraft flight trajectory using optimization procedures is considered. The proposed approach combines rough and ready analytical methods with numerical population-based optimization techniques, that results in significant reduction in computational time compared to existing methods that require boundary value problem solution and numerical integration of differential equations. The proposed approach to design a spacecraft flight scheme utilizes spheres of influence method, which involves segmenting the trajectory into several sections. Each section is represented as an orbit defined by a conic section. The first segment of the trajectory is a geocentric orbit of the spacecraft flight to the Moon. The second segment of the trajectory is a lunar orbit of spacecraft flight within the Moon sphere of influence. The last segment represents is the trajectory of the spacecraft leaving the Moon and returning to Earth along a geocentric orbit. To ensure a passive lunar flyby and subsequent return to Earth without using additional impulsive maneuvers, the parameters of each trajectory must be determined by the initial conditions. To do this the optimization problem was formulated aimed at determining the trajectory initial parameters. The cost function is the criteria for minimizing the spacecraft’s closest approach distance to the Moon and the total flight time. By varying the weight coefficients in the cost function, various trajectory configurations can be formulated. The result of the optimization problem solutions is the initial parameters of the flight trajectory to the Moon from Earth orbit were selected, ensuring the spacecraft’s entry into the Moon sphere of influence and enabling its return to Earth without impulsive maneuvers. The results show the fundamental applicability of the proposed approach to designing lunar missions using a genetic algorithm.
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Magnetic capacity in manganese sulfides with rare earth substitution Mn1-xRexS
Статья научная
Polycrystalline samples Mn1–xGdxS and Mn1–xYbxS with a concentration x = 0.2, near the concentration of ion flow through the fcc lattice, are studied in order to determine fluctuations in the valence of the ytterbium ion on dielectric properties. Dielectric constant and dielectric losses were determined from measurements of capacitance and loss tangent in the frequency range 102–106 Hz at temperatures of 80– 500 K without a magnetic field and in a magnetic field. The magnetic capacity and dielectric losses in the magnetic field of the sample were determined from the relative change in the real and imaginary parts of the dielectric constant of the sample in a magnetic field H = 12 kOe applied parallel to the capacitor plates. A temperature range with a sharp increase in dielectric constant and with a maximum dielectric loss has been discovered, which shifts with increasing frequency and magnetic field. An increase in dielectric constant and dielectric losses in a magnetic field above 170 K was found in Mn1-xYbxS. The increase in dielectric losses is explained by an increase in relaxation time, as a result of local deformations near ytterbium ions during valence fluctuations. The mechanism for reducing reactance in a magnetic field in Mn1–xYbxS at low frequencies due to capacitance, and at high frequencies due to inductance, has been determined. In the Mn0.8Gd0.2S compound, the imaginary part of the dielectric constant has two maxima. The low-temperature maximum shifts in a magnetic field towards high temperatures and is described in the model of localized electrons with freezing of dipole moments. Dielectric losses decrease in a magnetic field. The magnetic capacity decreases by an order of magnitude in Mn0.8Gd0.2S compared to Mn0.8Yb0.2S. The dielectric constant in both compounds is described in the Debye model with the activation dependence of the relaxation time on temperature, where the activation energies differ for ytterbium and gadolinium ions.
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Magnetic characteristics of iron nanoclusters
Статья научная
The study of the nanocrystalline state, which significantly changes most of the physical characteristics of sub-stances, is very relevant. Of great practical interest are the works devoted to the study of the magnetic character-istics of nanocrystals of ferromagnetic substances. It has already been shown that the size of iron nanocrystals significantly affects the magnitude of their magnetization. Nevertheless, an adequate model of the structure of nanocrystalline formations consisting of a different number of iron atoms, which allows us to describe the exper-imentally detected changes in the magnetic characteristics, has not yet been presented. In this paper, we analyze nanocrystalline iron clusters that are different in configuration and number of their constituent atoms. Spatial models of clusters are constructed using a three-dimensional modeling program, and the coordinates of individual atoms in the cluster are determined. The proposed structures of nanocrystals are based on tetrahedrally close-packed cluster assemblies of iron atoms. The electron state density spectra were con-structed for the proposed clusters. For this purpose, the theory of the electron density functional was used, the calculation was carried out by the method of scattered waves in accordance with the band theory of crystals. It is shown that the appearance of magnetization in tetrahedral densely packed cluster formations is associat-ed with the excited electronic states of the atoms located on the surface of the nanocluster. Excited atoms have an increased electron density, that is, electrons are able to transition to states with higher energy, approaching the Fermi energy. In this case, the Stoner criterion necessary for the occurrence of magnetization is fulfilled. The con-figurations of electrons with spin up and down differ, which is why uncompensated magnetic moments appear. It is confirmed that the proposed models of iron nanoclusters satisfactorily correspond to the known experimental data.
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Magnetic impedance in nonstichiometric manganese sulfide
Статья научная
The role of defects on the dynamic characteristics of manganese sulfide is studied by impedance spectroscopy in the frequency range 102–106 Hz and temperatures 80–500 K. Nonstoichiometry plays an important role in the formation of new transport and magnetic properties, as it leads to electrically inhomogeneous states. The phase composition and crystal structure of nonstoichiometric manganese sulfide were studied on a DRON-3 X-ray unit using CuKα – radiation at room temperature. According to X-ray diffraction analysis, the synthesized compound is single-phase and has a NaCl-type cubic lattice. From the frequency dependences of the impedance components measured in the absence of a field and in a magnetic field, the relaxation time of the current carriers in the Debye model is found. A sharp decrease in the relaxation time and its correlation with conductivity were found. The contribution to the impedance of the active and reactive parts of the impedance at frequencies below and above the relaxation time is established. The capacitance from the impedance hodograph in the equivalent circuit model is determined. In defective manganese sulfide, the temperature-dependent impedance has an activation character. The activation energy is determined in the range 250–500 K, which is attributed to the excitation energy of lattice polarons. The effect of a magnetic field on the dynamic characteristics of current carriers was studied as a result of a change in the impedance components in a magnetic field at fixed temperatures. The impedance increases in a magnetic field and reaches a maximum in the temperature range of charge ordering of vacancies. An increase in the impedance in a magnetic field is explained by a decrease in the diagonal component of the permittivity in a magnetic field in an electrically inhomogeneous medium. The experimental data are explained in the Debye model.
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Статья научная
Bismuth pyrostannate Bi2Sn2O7 is a diamagnet and belongs to the structural type of the A2B2O7 pyro-chlore class. In this class of compounds, in the presence of magnetic ions, very interesting magnetic proper-ties appear. Chromium- and iron-substituted bismuth pyrostannates Bi2(Sn0.9Me0.1)2O7, Me = Cr, and Fe were synthesized by solid-phase synthesis. X-ray diffraction analysis showed that the samples correspond to the Pc monoclinic cell of the Bi2Sn2O7 α-phase at room temperature. The magnetic properties up to 1100 K in magnetic fields up to 0.86 T and the electric polarization at frequencies of 10, 3, and 1 mHz in the tem-perature range 80–550 K have been studied. The effect of heterogeneous substitution by Cr3+ and Fe3+ ions on the magnetic properties and electric polarization of bismuth pyrostannate is investigated. An analysis of the experimental data revealed the dependence of the magnetic properties on the degree of filling of the elec-tron shells of chromium and iron ions. The Bi2(Sn0.9Cr0.1)2O7 compound exhibits ferromagnetic properties, while Bi2(Sn0.9Fe0.1)2O7 exhibits antiferromagnetic properties. In chromium-substituted bismuth pyrostan-nate during the α→β transition, the paramagnetic Curie temperature increases by a factor of 3. The temper-ature dependence of the inverse magnetic susceptibility is characterized by hysteresis in the temperature range of 400–900 K. The reverse magnetic susceptibility of Bi2(Sn0.9Fe0.1)2O7 in the entire temperature range is satisfactorily described by the Curie-Weiss law. Studies of the magnetic properties have established that the Fe3+ ions are in a high-spin state. The polarization hysteresis in Bi2(Sn0.9Cr0.1)2O7 is found, which shifts along the polarization axis and depends on temperature. Bi2(Sn1-xFex)2O7, x=0.1 is characterized by a linear field dependence. With an increase in the concentration of iron ions, a hysteresis arises in the field dependence of the electric polarization. The hysteresis of polarization in Bi2(Sn0.9Cr0.1)2O7 which depends on temperature was found. The nonlinear field dependence of the polarization in Bi2(Sn0.8Fe0.2)2O7 can be ex-plained by the interaction of the dipole and migration polarizations and the presence of oxygen vacancies. For the Bi2(Sn0.9Cr0.1)2O7 compound, a transition to the dipole glass state was found. In the β-phase of Bi2(Sn0.8Fe0.2)2O7 above T = 400 K, no polarization hysteresis is observed and the electron-relaxation polar-ization predominates. The mechanism of the occurrence of electronic polarization is explained with the ap-pearance of anionic vacancies upon heterogeneous substitution of tin ions.
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Magnetic properties of Mn1-xGdxSe sol-id solutions
Статья научная
Potential materials for spintronics operating under extreme conditions based on manganese selenides substituted with gadolinium are investigated. The technology of synthesis of solid solutions based on solid-phase reactions using MnSe and GdSe compounds is presented. As a result, Mn1-xGdxSe solid solutions with concentrations x = 0.05; 0.1; 0.15 and 0.5 were synthesized. The synthesis was carried out under vac-uum conditions of 10–2 Pa. The products of the primary synthesis were subjected to thorough grinding into powders, from which tablets were made under pressure for homogenizing annealing at 1370 K. After two hours of exposure, the synthesis products were tempered in cold water. At the final stage, homogeneous strong ingots of greyish-silver color were obtained. X-ray phase analysis of synthesized solid solutions of the Mn1-xGdxSe system was performed in Cu-K radiation in the point-by-point measurement mode with a scanning step along the angle Δ2θ = 0,03 degree; the time of information collection at the reference point Δτ =3 seconds. The spatial symmetry group and the parameter of the elementary crystal cell of solid solu-tions of the Mn1–xGdxSe system from X-ray diffraction analysis are determined. The dependence of the pa-rameter value of the crystal lattice of solid solutions on the concentration of gadolinium ions is found. The specific magnetization was measured by the ponderomotor method in a magnetic field with an induction of B = 0.86 Tesla and the magnetic susceptibility of the samples was determined in the temperature range of 80 ≤ T ≤ 950 K. The cycles carried out in the heating - cooling mode did not detect a change in properties. The Neel temperatures and the paramagnetic Curie temperature are determined from the Curie – Weiss law depending on the concentration of a rare earth element. A decrease in the temperature of the magnetic phase transition is established.
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